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src="/statics/digital/js/icheck.js"></script> <div id="abtflrvkdi" class="content bg-f7 w_min_1200"> <div id="abtflrvkdi" class="width_1200 m_0_auto p_b_60">  <p class="self-crumbs"> <span id="abtflrvkdi" class="note">您的位置：</span> <a class="link" href="/index-index.html" target="_blank">首頁</a> <span id="abtflrvkdi" class="gt">></span> <a class="link" href="/news-index.html" target="_blank">打印知識(shí)庫</a> <span id="abtflrvkdi" class="gt">></span> <span id="abtflrvkdi" class="current">材料資訊</span> </p>  <div id="abtflrvkdi" class="detail-section"> <h3 class="title">＂3D打?。⒏呷∠蛞壕Ц叻肿?/h3> <div id="abtflrvkdi" class="detail-text-container"><p> “3D打印”如此前沿的科技相信大家一定不陌生吧。利用這項(xiàng)技術(shù)，我們可以將打印材料層層堆疊得到藍(lán)圖所設(shè)計(jì)的物品。</p><p><img src="/uploadData/article/20190606100931854.jpg" title="1-1Z6041503151A.jpg" /></p><p>3D打印高分子——取向or非取向<br /> 隨著3D打印的發(fā)展，對(duì)高分子的3D打印技術(shù)也是日漸成熟。目前3D打印的高分子已經(jīng)能夠達(dá)到非常精細(xì)和復(fù)雜的結(jié)構(gòu)，但是其力學(xué)性能往往較差。這是因?yàn)楦叻肿拥娜∠蚨群艿?，甚至沒有取向。<br /> 通過取向，可以大幅提高高分子在取向方向上的力學(xué)性能、光學(xué)性能等等。楊氏模量在數(shù)值上甚至可以達(dá)到四個(gè)數(shù)量級(jí)的差距。<br />熱致性芳香族聚酯液晶（LCP）<br /> 熱致性芳香族聚酯液晶（LCP）在溫度高于材料熔點(diǎn)的條件下可自組裝形成高度取向域，這樣的特點(diǎn)使得LCP在3D打印的過程——熔融、擠出過程中更容易取向，從而打印出了高取向度的高性能液晶高分子。</p><p><img src="/uploadData/article/20190606100955633.jpg" title="1-1Z604150325321.jpg" /></p><p>"殼式"結(jié)構(gòu)<br /> 在打印的過程中，由于靠近表面的LCP散熱較快，LCP的取向得以固定。但靠近核心的區(qū)域仍然有較高的溫度，解取向作用仍然很強(qiáng)烈，LCP只有部分取向。這使得打印出來的纖維類似于一種“殼式”結(jié)構(gòu)。在這種結(jié)構(gòu)中不同取向程度使得它們?cè)诓煌姆较蛏铣尸F(xiàn)出不同的力學(xué)性能，當(dāng)較為脆弱的殼斷裂時(shí)，其核心仍能保持完好維持一定的力學(xué)性能。</p><p><img src="/uploadData/article/20190606101026345.png" title="1505364511-2.png" /></p><p><img src="/uploadData/article/20190606101050704.jpg" title="1-1Z604150335526.jpg" /></p><p>噴嘴參數(shù)對(duì)纖維力學(xué)性能的影響<br />【1】噴嘴直徑（dN）<br />噴嘴直徑增加，纖維的力學(xué)性能有所下降，這是由于中心高溫區(qū)占比較大，導(dǎo)致取向度最高的殼層的占比下降，使得總體平均取向度下降。<br />【2】厚度（h）<br />厚度越厚，纖維的力學(xué)性能也有所下降，也是由于殼層的占比下降導(dǎo)致總體平均取向度下降。<br /><br />【3】噴嘴溫度（TN）<br />溫度越高，纖維的力學(xué)性能也有所下降，溫度高使得中心的解取向作用較為強(qiáng)烈，導(dǎo)致總體平均取向度的降低。</p><p><img src="/uploadData/article/20190606101130834.jpg" title="1-1Z60415034DD.jpg" /></p><p>結(jié)語<br /> 在3D打印過程中，熱致液晶高分子所表現(xiàn)出的高取向性以及所形成的獨(dú)特核殼結(jié)構(gòu)。使得生產(chǎn)的纖維具有優(yōu)異力學(xué)性能。比目前普遍常用的3D打印的高分子力學(xué)性能高出幾個(gè)數(shù)量級(jí)。為未來航天、生物醫(yī)用等領(lǐng)域制備輕質(zhì)高強(qiáng)度材料帶來了無限的可能。</p></div> <div id="abtflrvkdi" class="function-bar"> <a class="collection-btn">收藏</a> </div>  <div id="abtflrvkdi" class="share-bar"> <span id="abtflrvkdi" class="add-time">發(fā)布時(shí)間：2019-06-06</span> <p class="do-share"> <span id="abtflrvkdi" class="note">分享到：</span> <a class="jq_share weixin" data-id="3670">微信</a> <a class="jq_share xinlang">新浪</a> <a class="jq_share weibo">微博</a> <a class="jq_share zone">空間</a> </p> </div>  <div id="abtflrvkdi" class="prev-next-page"> <a class="prev-page" href="/news-info-id-3689.html">上一篇：多波長(zhǎng)光固化3D打印多種樹脂材料</a> <a class="next-page" 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